Chapter 13. Thermolytic Formation and Trapping of Silenes Strongly Influenced by Reversed Polarization

  1. Prof. Dr. Norbert Auner2 and
  2. Prof. Dr. Johann Weis3
  1. Henrik Ottosson,
  2. Tamaz Guliashvili and
  3. Ibrahim El-Sayed

Published Online: 5 MAY 2008

DOI: 10.1002/9783527619924.ch13

Organosilicon Chemistry V: From Molecules to Materials

Organosilicon Chemistry V: From Molecules to Materials

How to Cite

Ottosson, H., Guliashvili, T. and El-Sayed, I. (2003) Thermolytic Formation and Trapping of Silenes Strongly Influenced by Reversed Polarization, in Organosilicon Chemistry V: From Molecules to Materials (eds N. Auner and J. Weis), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527619924.ch13

Editor Information

  1. 2

    Department of Inorganic Chemistry, University of Frankfurt, Marie-Curie-Straße 11, 60439 Frankfurt am Main, Germany

  2. 3

    Consortium of Electrochemical Industry GmbH, Zielstattstraße 20, 81379 Munich, Germany

Author Information

  1. Department of Organic Chemistry Box 599, Uppsala University, 751 24 Uppsala, Sweden Tel: +46 18 471 3809 — Fax: +46 18 471 3818

Publication History

  1. Published Online: 5 MAY 2008
  2. Published Print: 26 SEP 2003

ISBN Information

Print ISBN: 9783527306701

Online ISBN: 9783527619924

SEARCH

Keywords:

  • silenes;
  • reversed polarization;
  • DFT;
  • rearrangements

Summary

The thermal rearrangement of silylamides into 1,1-bis(trimethylsilyl)-2-amino-2-trimethylsilyloxysilenes and their subsequent trapping by 2,-dimethyl-1,3 -butadiene were investigated both computationally and experimentally, with focus on the geometric and electronic structure of these silenes.