Chapter 76. Dipolar 1,2-N,N-Dimethylaminomethylferrocenyl Complexes for Nonlinear Optics?

  1. Prof. Dr. Norbert Auner3 and
  2. Prof. Dr. Johann Weis4
  1. Christian Beyer1,
  2. Uwe Böhme1,
  3. Gerhard Roewer1 and
  4. Claus Pietzsch2

Published Online: 5 MAY 2008

DOI: 10.1002/9783527619924.ch76

Organosilicon Chemistry V: From Molecules to Materials

Organosilicon Chemistry V: From Molecules to Materials

How to Cite

Beyer, C., Böhme, U., Roewer, G. and Pietzsch, C. (2003) Dipolar 1,2-N,N-Dimethylaminomethylferrocenyl Complexes for Nonlinear Optics?, in Organosilicon Chemistry V: From Molecules to Materials (eds N. Auner and J. Weis), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527619924.ch76

Editor Information

  1. 3

    Department of Inorganic Chemistry, University of Frankfurt, Marie-Curie-Straße 11, 60439 Frankfurt am Main, Germany

  2. 4

    Consortium of Electrochemical Industry GmbH, Zielstattstraße 20, 81379 Munich, Germany

Author Information

  1. 1

    Institut für Anorganische Chemie, Technische Universität Bergakademie Freiberg Leipziger Straße 29, D-09596 Freiberg, Germany Tel.: +49 3731 39 4346 — Fax: +49 3731 39 4058

  2. 2

    Institut für Angewandte Physik, Technische Universität Bergakademie Freiberg Bernhard-von-Cotta-Straße 4, D-09596 Freiberg Germany

Publication History

  1. Published Online: 5 MAY 2008
  2. Published Print: 26 SEP 2003

ISBN Information

Print ISBN: 9783527306701

Online ISBN: 9783527619924

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Keywords:

  • 1,2-N,N-dimethylaminomethylferrocenyl;
  • ferrocene;
  • charge transfer;
  • silicon;
  • Mössbauer spectroscopy

Summary

A series of substituted 1,2-N,N-(dimefhylaminomethyl)ferrocenyl compounds with organic acceptor groups were synthesized and characterized by 1H NMR, 13C NMR, 29Si NMR, ES-MS, IR, UV/Vis and 57Fe Mössbauer spectroscopy. The final products are stable in air. X-ray structure analyses of compounds with two or one phenyl groups are not so easily accessible, therefore crystalline derivatives were obtained by using hydrogen chloride or picric acid. 57Fe Mössbauer spectroscopy gives strong evidence of a significant electronic coupling between the ferrocenyl unit and the organic acceptor moiety of the molecules in the ground state. Such compounds should have some special optical properties.