Chapter 88. Synthesis of Chiral Amino-Substituted Organosilanes

  1. Prof. Dr. Norbert Auner2 and
  2. Prof. Dr. Johann Weis3
  1. Uwe Böhme,
  2. Betty Günther and
  3. Ben Rittmeister

Published Online: 5 MAY 2008

DOI: 10.1002/9783527619924.ch88

Organosilicon Chemistry V: From Molecules to Materials

Organosilicon Chemistry V: From Molecules to Materials

How to Cite

Böhme, U., Günther, B. and Rittmeister, B. (2003) Synthesis of Chiral Amino-Substituted Organosilanes, in Organosilicon Chemistry V: From Molecules to Materials (eds N. Auner and J. Weis), Wiley-VCH Verlag GmbH, Weinheim, Germany. doi: 10.1002/9783527619924.ch88

Editor Information

  1. 2

    Department of Inorganic Chemistry, University of Frankfurt, Marie-Curie-Straße 11, 60439 Frankfurt am Main, Germany

  2. 3

    Consortium of Electrochemical Industry GmbH, Zielstattstraße 20, 81379 Munich, Germany

Author Information

  1. Institut für Anorganische Chemie, Technische Universität Bergakademie Freiberg Leipziger Straße 29, D-09596 Freiberg, Germany

Publication History

  1. Published Online: 5 MAY 2008
  2. Published Print: 26 SEP 2003

ISBN Information

Print ISBN: 9783527306701

Online ISBN: 9783527619924

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Keywords:

  • amides;
  • silanes;
  • disilanes;
  • aminosilanes;
  • stereochemistry

Summary

Defined crystalline amino-substituted organosilanes were prepared by reaction of N-methylaniline with 1,1,2,2-tetrachlorodimethyldisilane and other chloroorganosilanes. The X-ray structure analyses of 1,2-dichloro-1,2-bis(N-methyl-anilino)dimethyldisilane (1), 1-chloro-1,2,2-tris(N-methylanilino)dimethyldisilane (2) and tetrakis(N-methylanilino)-1,2-dimethyldisilane (3) were performed. The absolute structure of 1 was determined by crystallographic methods. 1,2-Dichloro -1,2-bis(N-methylanilino)dimethyldisilane (1) is a useful reagent for the preparation of a variety of other aminoorganodisilanes.