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Chapter 6. Transition-metal Nanoparticle Catalysis in Imidazolium Ionic Liquids

  1. Prof. Dr. Didier Astruc
  1. Jairton Dupont,
  2. Dagoberto de Oliveira Silva

Published Online: 16 JAN 2008

DOI: 10.1002/9783527621323.ch6

Nanoparticles and Catalysis

Nanoparticles and Catalysis

How to Cite

Dupont, J. and Silva, D. d. O. (2008) Transition-metal Nanoparticle Catalysis in Imidazolium Ionic Liquids, in Nanoparticles and Catalysis (ed D. Astruc), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany. doi: 10.1002/9783527621323.ch6

Editor Information

  1. Université de Bordeaux I, Institut des Sciences, Moléculaires, UMR CNRS, N° 5255, 351 Cours de la Liberation, 33405 Talence Cedex, France

Author Information

  1. Laboratory of Molecular Catalysis, Institute of Chemistry, UFRGS, Av. Bento Gonçalves, 9500 Porto Alegre, 91501-970 RS, Brazil

Publication History

  1. Published Online: 16 JAN 2008
  2. Published Print: 17 OCT 2007

ISBN Information

Print ISBN: 9783527315727

Online ISBN: 9783527621323

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Keywords:

  • transition-metal nanoparticles;
  • catalysis;
  • imidazolium ionic liquids;
  • structural aspects;
  • stabilization;
  • catalytic properties;
  • perspectives

Summary

This chapter contains sections titled:

  • Introduction

  • Ionic Liquids: Structural Aspects

  • Formation of Nanoparticles in Imidazolium Ionic Liquids

  • Stabilization of the Metal Nanoparticles in Imidazolium Ionic Liquids

    • Analysis of the Isolated Nanoparticles (XRD and XPS)

    • Analysis of the MNPs Dispersed in Ionic Liquids

    • H/D and D/H Labeling Experiments

    • MNPs in Ionic Liquid/Additive Ligands or Polymeric Stabilizers

  • Catalytic Properties of Transition-metal Nanoparticles in Ionic Liquids

    • Hydrogenation of Alkenes and Ketones

    • Hydrogenation of Ketones

    • Hydrogenations of Arenes

    • Miscellaneous Reactions

  • Conclusions and Perspectives