• Please log in or register to access this feature.

Chapter 1. Bite Angle Effects of Diphosphines in Carbonylation Reactions

  1. Prof. László Kollár
  1. Piet W. N. M. van Leeuwen,
  2. Zoraida Freixa

Published Online: 14 FEB 2008

DOI: 10.1002/9783527621545.ch1

Book Title

Modern Carbonylation Methods

Modern Carbonylation Methods

Additional Information

How to Cite

Leeuwen, P. W. N. M. v. and Freixa, Z. (2008) Bite Angle Effects of Diphosphines in Carbonylation Reactions, in Modern Carbonylation Methods (ed L. Kollár), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany. doi: 10.1002/9783527621545.ch1

Editor Information

  1. University of Pécs, Department of Inorganic Chemistry, Ifjúság u. 6, 7624 Pécs, Hungary

Author Information

  1. Universiteit van Amsterdam, Van't hoff Institute for Molecular Sciences, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands

Publication History

  1. Published Online: 14 FEB 2008
  2. Published Print: 12 MAR 2008

ISBN Information

Print ISBN: 9783527318964

Online ISBN: 9783527621545

SEARCH

CHAPTER TOOLS

Get PDF (517K)

Keywords:

  • modern carbonylation methods;
  • bite angle effect;
  • diphosphines;
  • rhodium-catalyzed hydroformylation;
  • platinum-catalyzed alkene hydroformylation;
  • palladium-catalyzed CO/ethene copolymerization;
  • rhodium-catalyzed methanol carbonylation;
  • ligand-modified Monsanto process

Summary

This chapter contains sections titled:

  • Introduction

  • Rhodium-Catalyzed Hydroformylation

    • Introduction

    • Steric Bite Angle Effect and Regioselectivity

    • Electronic Bite Angle Effect and Activity

    • Isotope Effects [24]

  • Platinum-Catalyzed Alkene Hydroformylation

  • Palladium-Catalyzed CO/Ethene Copolymerization

    • Polyketone Formation

    • Chain Transfer Mechanisms (Initiation–Termination)

    • Methyl Propanoate Formation

    • Theoretical Support

  • Rhodium-Catalyzed Methanol Carbonylation: the Ligand-Modified Monsanto Process

  • References

Get PDF (517K)