Chapter 11. Oxidation Reactions over Supported Metal Oxide Catalysts: Molecular/Electronic Structure – Activity/Selectivity Relationships

  1. Prof. S. David Jackson and
  2. Dr. Justin S. J. Hargreaves
  1. Israel E. Wachs and
  2. Taejin Kim

Published Online: 26 MAR 2009

DOI: 10.1002/9783527626113.ch11

Metal Oxide Catalysis

Metal Oxide Catalysis

How to Cite

Wachs, I. E. and Kim, T. (2008) Oxidation Reactions over Supported Metal Oxide Catalysts: Molecular/Electronic Structure – Activity/Selectivity Relationships, in Metal Oxide Catalysis (eds S. D. Jackson and J. S. J. Hargreaves), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany. doi: 10.1002/9783527626113.ch11

Editor Information

  1. University of Glasgow, Department of Chemistry, WestCHEM, Joseph Black Building, Glasgow, G12 8QQ, United Kingdom

Author Information

  1. Lehigh University, Chemical Engineering Department, Operando Molecular Spectroscopy & Catalysis Laboratory, Bethlehem, PA 18015, USA

Publication History

  1. Published Online: 26 MAR 2009
  2. Published Print: 15 OCT 2008

ISBN Information

Print ISBN: 9783527318155

Online ISBN: 9783527626113

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Keywords:

  • Supported metal oxide catalysts;
  • Molecular/electronic structure–activity relationships;
  • Surface reactivity;
  • Steady-state reactivity;
  • Role of surface acid sites;
  • VO4 species

Summary

This chapter contains sections titled:

  • Overview

  • Introduction

  • Monolayer Surface Coverage

  • Molecular and Electronic Structures

  • Number of Exposed Catalytic Active Sites (Ns)

  • Surface Reactivity

  • Steady-State Reactivity (TOF)

  • Number of Participating Catalytic Active Sites in Oxidation Reactions

  • Role of Surface Acid Sites on Oxidation Reactions

  • Other Supported MOx Redox Active and Acidic Systems

  • Conclusions

  • Acknowledgments

  • References