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Coupling Reactions and Separation in Tunable Fluids: Phase Transfer-Catalysis and Acid-catalyzed Reactions

Part 4. Supercritical Solvents

  1. Pamela Pollet,
  2. Jason P. Hallett,
  3. Charles A. Eckert,
  4. Charles L. Liotta

Published Online: 15 JUL 2010

DOI: 10.1002/9783527628698.hgc045

Handbook of Green Chemistry

Handbook of Green Chemistry

How to Cite

Pollet, P., Hallett, J. P., Eckert, C. A. and Liotta, C. L. 2010. Coupling Reactions and Separation in Tunable Fluids: Phase Transfer-Catalysis and Acid-catalyzed Reactions. Handbook of Green Chemistry. 4:12:435–455.

Author Information

  1. Georgia Institute of Technology, School of Chemical and Biomolecular Engineering, School of Chemistry and Biochemistry Specialty Separations Cente, Atlanta, GA, USA

Publication History

  1. Published Online: 15 JUL 2010

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Abstract

The sections in this article are

  • Introduction
  • Phase Transfer Catalysis
    • Background
    • Phase Transfer Catalysis Quaternary Ammonium Salt-catalyzed Reactions
    • PTC Separation and Recycling Using CO2
  • Near-critical Water
    • Definition
    • Properties
    • Friedel–Crafts Chemistry in NCW
  • Alkylcarbonic Acids
    • Probing Alkylcarbonic Acids – Alkylcarbonic Acids with Diazodiphenylmethane (DDM)
    • Reactions Using Alkylcarbonic Acids
      • Ketal Formation
      • Formation of Diazonium Salts
  • Conclusion

Keywords:

  • supercritical fluid;
  • coupling reactions;
  • phase transfer catalysis;
  • acid-catalyzed reactions;
  • supercritical carbon dioxide