Standard Article

Green Acid Catalysis in Water

Part 5. Reactions in Water

  1. Chikako Ogawa,
  2. Shū Kobayashi

Published Online: 15 JUL 2010

DOI: 10.1002/9783527628698.hgc048

Handbook of Green Chemistry

Handbook of Green Chemistry

How to Cite

Ogawa, C. and Kobayashi, S. 2010. Green Acid Catalysis in Water. Handbook of Green Chemistry. 5:2:31–56.

Author Information

  1. The University of Tokyo, School of Science and Graduate School of Pharmaceutical Sciences, Department of Chemistry, Hongo, Bunkyo-ku, Tokyo, Japan

  1. Eisai Research Institute, Lead Identification, Andover, MA, USA

Publication History

  1. Published Online: 15 JUL 2010

Chemistry Terms

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Abstract

The sections in this article are

  • Introduction
  • Lewis Acids in Water
    • Introduction. Lewis Acids in Aqueous Media: Possible?
    • Lewis Acid Catalysis in Water as “Sole Solvent”
      • LASC: Lewis Acid–Surfactant Combined Catalyst
      • Polymer-supported Scandium Triflate
      • Silica Gel-supported Scandium with Ionic Liquid
  • Chiral Lewis Acid-catalyzed Asymmetric Reactions in Water
    • Mannich-type Reactions in Water
    • Michael Reaction in Water
    • Epoxide Ring-opening Reaction in Water
    • Hydroxymethylation in Water
  • Brønsted Acid Catalysis in Pure Water
    • Surfactant-type Brønsted Acid Catalysts
    • Polymer-supported Brønsted Acid Catalysts
  • Conclusion and Perspective

Keywords:

  • water;
  • solvent;
  • acid catalysis;
  • Lewis acid catalysis;
  • Brønsted acid catalysis;
  • scandium;
  • green chemistry

Featured Compounds

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  1. 1 - 48
Compound 1
Molecular Weight:170.3241
Molecular Formula:C9H18OSi
InChIKey:SBEMOANGDSSPJY-UHFFFAOYSA-N
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Compound 2
Molecular Weight:206.3562
Molecular Formula:C12H18OSi
InChIKey:ZCNQIKXAMNBENN-XGICHPGQSA-N
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Compound 3
Molecular Weight:791.711
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 4a
Molecular Weight:603.39
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 5
Molecular Weight:204.405
Molecular Formula:C9H20OSSi
InChIKey:WHDITUCCFADHLG-UHFFFAOYSA-N
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Compound 4b
Molecular Weight:603.39
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 4c
Molecular Weight:1303.495
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 6
Molecular Weight:220.2246
Molecular Formula:C11H12N2O3
InChIKey:IIWKUEWCQDJOID-XYOKQWHBSA-N
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Compound 7
Molecular Weight:452.5873
Molecular Formula:C30H32N2O2
InChIKey:LCIYWEQCHULBIH-LOYHVIPDSA-N
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Compound 25
Molecular Weight:184.2322
Molecular Formula:C10H16O3
InChIKey:OGIKPUCMXHEUMK-UHFFFAOYSA-N
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Compound 8
Molecular Weight:328.4485
Molecular Formula:C20H28N2O2
InChIKey:Not Available
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Compound 9
Molecular Weight:232.3935
Molecular Formula:C14H20OSi
InChIKey:GTYDJWAEPGBRPB-UHFFFAOYSA-N
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Compound 10
Molecular Weight:218.3669
Molecular Formula:C13H18OSi
InChIKey:Not Available
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Compound 11
Molecular Weight:220.3828
Molecular Formula:C13H20OSi
InChIKey:QYRMSDNYFLDYEE-LCYFTJDESA-N
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Compound 12
Molecular Weight:240.801
Molecular Formula:C12H17ClOSi
InChIKey:RJVWZWAXRKBCMI-XGICHPGQSA-N
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Compound 13
Molecular Weight:236.3822
Molecular Formula:C13H20O2Si
InChIKey:PFARRSQEWUBOJG-MLPAPPSSSA-N
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Compound 14
Molecular Weight:184.3507
Molecular Formula:C10H20OSi
InChIKey:FCNOWHQIHFADKQ-UHFFFAOYSA-N
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Compound 20
Molecular Weight:218.432
Molecular Formula:C10H22OSSi
InChIKey:HUKXSJOQHXCBBH-CMDGGOBGSA-N
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Compound 21
Molecular Weight:232.458
Molecular Formula:C11H24OSSi
InChIKey:ROORVTSXALTAMK-MDZDMXLPSA-N
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Compound 15
Molecular Weight:220.3828
Molecular Formula:C13H20OSi
InChIKey:HYIITTBRSVOXNA-MLPAPPSSSA-N
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Compound 16
Molecular Weight:226.775
Molecular Formula:C11H15ClOSi
InChIKey:SNOMRDCHVWVVAG-WCIBSUBMSA-N
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Compound 17
Molecular Weight:222.3556
Molecular Formula:C12H18O2Si
InChIKey:LZYKIBXNPBVMRI-XGICHPGQSA-N
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Compound 18
Molecular Weight:232.3935
Molecular Formula:C14H20OSi
InChIKey:UVQGKEOKBRFIBE-UHFFFAOYSA-N
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Compound 19
Molecular Weight:170.3241
Molecular Formula:C9H18OSi
InChIKey:JLDDBLMJAAMMRE-UHFFFAOYSA-N
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Compound 22
Molecular Weight:192.3296
Molecular Formula:C11H16OSi
InChIKey:NWKOSZXWEHUEDG-WCIBSUBMSA-N
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Compound 24
Molecular Weight:176.2548
Molecular Formula:C12H16O
InChIKey:UWSPWQQZFOSTHS-LBPRGKRZSA-N
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Compound 26
Molecular Weight:318.3643
Molecular Formula:C18H22O5
InChIKey:VFIVCPZYSDCZKN-UHFFFAOYSA-N
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Compound 27
Molecular Weight:297.393
Molecular Formula:C22H19N
InChIKey:DIPLVCWFEVMXLU-UHFFFAOYSA-N
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Compound 28
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 28a
Molecular Weight:547.6833
Molecular Formula:C36H37NO4
InChIKey:PPDKIXXPJFKXKI-RQJNEPOFSA-N
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Compound 28b
Molecular Weight:570.672
Molecular Formula:C35H38O7
InChIKey:PIBWJKCPFYASMB-KIPVPBBYSA-N
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Compound 29
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 30
Molecular Weight:398.271
Molecular Formula:C20H17BrFN3
InChIKey:LUWGVOJFHFMVCW-UHFFFAOYSA-N
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Compound 31
Molecular Weight:354.4012
Molecular Formula:C23H18N2O2
InChIKey:SVEJYYUKKJRQCO-UHFFFAOYSA-N
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Compound 32
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 33
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 34
Molecular Weight:378.4657
Molecular Formula:C26H22N2O
InChIKey:VLWPWVHVJMMEKL-UHFFFAOYSA-N
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Compound 35
Molecular Weight:387.4757
Molecular Formula:C27H21N3
InChIKey:AGLJONDLZFUELN-UHFFFAOYSA-N
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Compound 36
Molecular Weight:402.4871
Molecular Formula:C28H22N2O
InChIKey:CACFPIZOOALJCL-UHFFFAOYSA-N
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Compound 37
Molecular Weight:406.5188
Molecular Formula:C28H26N2O
InChIKey:LQKBXXCURFSYNA-UHFFFAOYSA-N
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Compound 38
Molecular Weight:365.49
Molecular Formula:C25H19NS
InChIKey:BTWDZLMJGCLWAH-UHFFFAOYSA-N
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Compound 39
Molecular Weight:297.393
Molecular Formula:C22H19N
InChIKey:CREGCEGSAKOZJS-UHFFFAOYSA-N
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Compound 40
Molecular Weight:375.4617
Molecular Formula:C27H21NO
InChIKey:QGRLBEZBRVMTRV-UHFFFAOYSA-N
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Compound 41
Molecular Weight:378.4657
Molecular Formula:C26H22N2O
InChIKey:ZXCAFXLSBURAST-UHFFFAOYSA-N
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Compound 44
Molecular Weight:157.167
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 45
Molecular Weight:425.688
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 43
Molecular Weight:157.167
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 46
Molecular Weight:425.688
Molecular Formula:Not Available
InChIKey:Not Available
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  1. 1 - 48