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Water Under Extreme Conditions for Green Chemistry

Part 5. Reactions in Water

  1. Phillip E. Savage,
  2. Natalie A. Rebacz

Published Online: 15 JUL 2010

DOI: 10.1002/9783527628698.hgc057

Handbook of Green Chemistry

Handbook of Green Chemistry

How to Cite

Savage, P. E. and Rebacz, N. A. 2010. Water Under Extreme Conditions for Green Chemistry. Handbook of Green Chemistry. 5:11:331–361.

Author Information

  1. University of Michigan, Chemical Engineering Department, Ann Arbor, MI, USA

Publication History

  1. Published Online: 15 JUL 2010

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Abstract

The sections in this article are

  • Introduction
  • Background
    • Properties of HTW
    • Process Engineering Considerations
    • Theoretical, Computational, and Experimental Methods
      • Classical Theory
      • Molecular and Computational Modeling
      • Experimental Methods
    • pH Effects
  • Recent Progress in HTW Synthesis
    • Hydrogenation
    • C[BOND]C Bond Formation
      • Friedel–Crafts Alkylation
      • Heck Coupling
      • Nazarov Cyclization
    • Condensation
    • Hydrolysis
    • Rearrangements
    • Hydration/Dehydration
    • Elimination
    • Partial Oxidation to Form Carboxylic Acids
    • C[BOND]C Bond Cleavage
    • H–D Exchange
    • Amidation
  • Acknowledgments

Keywords:

  • water;
  • high-temperature water;
  • supercritical water;
  • organic synthesis;
  • green chemistry