Standard Article

Atom Economy: a Challenge for Enhanced Synthetic Efficiency

Part 7. Green Synthesis

  1. Barry M. Trost

Published Online: 15 APR 2012

DOI: 10.1002/9783527628698.hgc072

Handbook of Green Chemistry

Handbook of Green Chemistry

How to Cite

Trost, B. M. 2012. Atom Economy: a Challenge for Enhanced Synthetic Efficiency. Handbook of Green Chemistry. 7:1:1–35.

Author Information

  1. Stanford University, Department of Chemistry, Stanford, CA, USA

Publication History

  1. Published Online: 15 APR 2012

Abstract

The sections in this article are

  • Vinylidenes
    • Cycloisomerization of Hydroxyalkynes
    • Reconstitutive Condensation
  • Redox Isomerization
    • Allyl Alcohols
  • Ruthenacyclopentadiene Intermediates
  • Ruthenacyclopentene Intermediates
    • Intermolecular Alkene-Alkyne Coupling
    • Butenolide Formation and Related Reactions
    • Pyran Formation
    • Intramolecular Alkene–Alkyne Coupling
    • [5 + 2] Cycloaddition
    • Vinyl Ketones as Alkyne Partners
  • Allylic C–H Insertion
  • Reactions of Alkenes
    • Allene–Alkene Coupling
    • Heterocycles via Allene–Alkene Coupling
  • Conclusion
  • Acknowledgments

Keywords:

  • atom economy;
  • synthetic efficiency;
  • ruthenium complexes;
  • green chemistry

Featured Compounds

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  1. 1 - 47
Compound 1
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 3
Molecular Weight:472.5721
Molecular Formula:C30H32O5
InChIKey:PBWWUIGNFQKULA-PGVCKJCBSA-N
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Compound 2
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 4
Molecular Weight:270.4076
Molecular Formula:C16H30O3
InChIKey:XQPFRDLDHNFCCR-GJZGRUSLSA-N
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Compound 5
Molecular Weight:312.4443
Molecular Formula:C18H32O4
InChIKey:SPOXUSGCKOQPRB-SJORKVTESA-N
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Compound 6
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 8
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 10
Molecular Weight:150.2176
Molecular Formula:C10H14O
InChIKey:UTSGPHXOHJSDBC-UHFFFAOYSA-N
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Compound 12
Molecular Weight:214.3443
Molecular Formula:C13H26O2
InChIKey:DSESKJUXFCMPPW-UHFFFAOYSA-N
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Compound 13
Molecular Weight:214.3443
Molecular Formula:C13H26O2
InChIKey:WPTBUYVAXDDJCB-UHFFFAOYSA-N
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Compound 11
Molecular Weight:186.2912
Molecular Formula:C11H22O2
InChIKey:GKSDPBQHLXPSBV-UHFFFAOYSA-N
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Compound 14
Molecular Weight:240.3386
Molecular Formula:C14H24O3
InChIKey:NXUPAFRILXOQBP-ZHACJKMWSA-N
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Compound 15
Molecular Weight:776.25
Molecular Formula:C45H37ClP2Ru
InChIKey:XQEXXPMLCIMJIH-UHFFFAOYSA-M
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Compound 17
Molecular Weight:200.2762
Molecular Formula:C14H16O
InChIKey:FUFMQDPEADAKMD-OKILXGFUSA-N
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Compound 16
Molecular Weight:434.28
Molecular Formula:C11H14F6N3PRu
InChIKey:NXLHHENYDLKNIP-UHFFFAOYSA-N
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Compound 18
Molecular Weight:400.5525
Molecular Formula:C28H32O2
InChIKey:GSIAWYHQJLSMTH-XHKRZFAGSA-N
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Compound 19
Molecular Weight:400.5525
Molecular Formula:C28H32O2
InChIKey:GSIAWYHQJLSMTH-WEJQDGASSA-N
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Compound 20
Molecular Weight:525.775
Molecular Formula:C29H39NO4SSi
InChIKey:LTTIPCOBGRYTHW-HHHXNRCGSA-N
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Compound 21
Molecular Weight:411.514
Molecular Formula:C23H25NO4S
InChIKey:LVHIIVCPCNFBEG-QHCPKHFHSA-N
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Compound 22
Molecular Weight:184.2338
Molecular Formula:C13H12O
InChIKey:YJNKUZSCEMXRKI-UHFFFAOYSA-N
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Compound 23
Molecular Weight:195.2597
Molecular Formula:C14H13N
InChIKey:YYXRZBOPZSLPHD-UHFFFAOYSA-N
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Compound 24
Molecular Weight:309.8
Molecular Formula:C13H17ClRu
InChIKey:QSMVQNGCQYEIKZ-PHFPKPIQSA-M
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Compound 27
Molecular Weight:256.338
Molecular Formula:C14H24O4
InChIKey:RXICCXXGAHSRRD-WDMOLILDSA-N
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Compound 28
Molecular Weight:216.2741
Molecular Formula:C11H20O4
InChIKey:XYECQJJZDLZIIY-NGZCFLSTSA-N
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Compound 29
Molecular Weight:322.4391
Molecular Formula:C19H30O4
InChIKey:IXHDDHRTZWDXDS-YVLHZVERSA-N
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Compound 31
Molecular Weight:165.2322
Molecular Formula:C10H15NO
InChIKey:PKPHLCQLWIITLN-GQCTYLIASA-N
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Compound 32
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 30
Molecular Weight:322.4391
Molecular Formula:C19H30O4
InChIKey:UXUNLBFQCRDGKK-DTQAZKPQSA-N
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Compound 33
Molecular Weight:128.1259
Molecular Formula:C6H8O3
InChIKey:GLVNZYODMKSEPS-ONEGZZNKSA-N
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Compound 34
Molecular Weight:166.3031
Molecular Formula:C12H22
InChIKey:IYPLTVKTLDQUGG-UHFFFAOYSA-N
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Compound 37
Molecular Weight:358.4712
Molecular Formula:C22H30O4
InChIKey:WUUFTDOABYKARY-YESGWAHASA-N
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Compound 38
Molecular Weight:362.503
Molecular Formula:C22H34O4
InChIKey:NBNKOPMYYYWKOW-ROUUACIJSA-N
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Compound 39
Molecular Weight:206.3669
Molecular Formula:C15H26
InChIKey:NBQUHCYKKOOVPE-ONNLMXTPSA-N
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Compound 40
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 43
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound 44
Molecular Weight:332.3909
Molecular Formula:C19H24O5
InChIKey:STYOOISSTONCCD-UPASJPCUSA-N
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Compound 49
Molecular Weight:156.2221
Molecular Formula:C9H16O2
InChIKey:PSPBJARYFGDEPM-UHFFFAOYSA-N
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Compound 50
Molecular Weight:226.312
Molecular Formula:C13H22O3
InChIKey:SWAOVYSAHHWHFT-FMIVXFBMSA-N
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Compound 51
Molecular Weight:307.3847
Molecular Formula:C17H25NO4
InChIKey:KUPIVQHZNNHVLQ-KRWDZBQOSA-N
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Compound 52
Molecular Weight:307.3847
Molecular Formula:C17H25NO4
InChIKey:KFHCMHBUOYVEPE-DJFLKLCTSA-N
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Compound 53
Molecular Weight:307.3847
Molecular Formula:C17H25NO4
InChIKey:KFHCMHBUOYVEPE-ILKPWURSSA-N
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Compound 54
Molecular Weight:282.3768
Molecular Formula:C19H22O2
InChIKey:NQDVYHYEWPICAH-UHOSZYNNSA-N
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Compound 55
Molecular Weight:282.3768
Molecular Formula:C19H22O2
InChIKey:MPROXRNCFMKNTL-ILTCNKJVSA-N
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Compound 58
Molecular Weight:264.36
Molecular Formula:C16H24O3
InChIKey:ATXRHNBFFIFIAJ-UHFFFAOYSA-N
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Compound 59
Molecular Weight:194.2701
Molecular Formula:C12H18O2
InChIKey:ZFLURNNYZMZUGY-UHFFFAOYSA-N
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Compound 60
Molecular Weight:264.36
Molecular Formula:C16H24O3
InChIKey:JGMNAIJTJIWHKG-RVDMUPIBSA-N
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Compound 61
Molecular Weight:437.528
Molecular Formula:C26H31NO5
InChIKey:GBVAUOINVCEZRZ-RINHOTFJSA-N
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  1. 1 - 47