Chapter 5. Poly(aryleneethynylene)s

  1. Prof. Mario Leclerc and
  2. Prof. Jean-François Morin
  1. Brett VanVeller and
  2. Timothy M. Swager

Published Online: 26 MAY 2010

DOI: 10.1002/9783527629787.ch5

Design and Synthesis of Conjugated Polymers

Design and Synthesis of Conjugated Polymers

How to Cite

VanVeller, B. and Swager, T. M. (2010) Poly(aryleneethynylene)s, in Design and Synthesis of Conjugated Polymers (eds M. Leclerc and J.-F. Morin), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany. doi: 10.1002/9783527629787.ch5

Editor Information

  1. CERMA, Département de Chimie, Université Laval, Quebec City, Quebec, G1V 0A6, Canada

Author Information

  1. Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139, USA

Publication History

  1. Published Online: 26 MAY 2010
  2. Published Print: 19 APR 2010

ISBN Information

Print ISBN: 9783527324743

Online ISBN: 9783527629787

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Keywords:

  • LUMO;
  • HOMO;
  • palladium;
  • sp2-hybridized;
  • side chain;
  • polymerization

Summary

This chapter contains sections titled:

  • Introduction

  • Palladium-Catalyzed Polymerizations

  • Different Palladium Schemes

  • Ortho and Meta PAEs

  • Macrocycles: an Introduction

  • Synthesis of Monodisperse and Sequence-Specific PAEs

  • Synthesis of Poly(phenylenebutadiynylenes) PPBs

  • Palladium-Mediated Synthesis: Limitations and Conclusions

  • Metathesis Polymerizations

  • Macrocycles: the Continued Story

  • Metathesis: Concluding Remarks

  • Transition-Metal-Free Polymerizations

  • More Complex Side-Chain Effects

  • Post-Polymerization Modification

  • Characterization of Poly(aryleneethynylene)

  • Conclusion

  • References