Chapter 5. Main Group Element- and Transition Metal-Promoted Carboxylation of Organic Substrates (Alkanes, Alkenes, Alkynes, Aromatics, and Others)

  1. Prof., Dr. Michele Aresta
  1. Thomas Zevaco and
  2. Eckhard Dinjus

Published Online: 25 JAN 2010

DOI: 10.1002/9783527629916.ch5

Carbon Dioxide as Chemical Feedstock

Carbon Dioxide as Chemical Feedstock

How to Cite

Zevaco, T. and Dinjus, E. (2010) Main Group Element- and Transition Metal-Promoted Carboxylation of Organic Substrates (Alkanes, Alkenes, Alkynes, Aromatics, and Others), in Carbon Dioxide as Chemical Feedstock (ed M. Aresta), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany. doi: 10.1002/9783527629916.ch5

Editor Information

  1. University of Bari, Department of Chemistry and CIRCC, 70126 Bari, Italy

Author Information

  1. Forschungszentrum Karlsruhe GmbH, Institute of Technical Chemistry, Division of Chemical–Physical Processing, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Publication History

  1. Published Online: 25 JAN 2010
  2. Published Print: 15 FEB 2010

ISBN Information

Print ISBN: 9783527324750

Online ISBN: 9783527629916

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Keywords:

  • Carboxylic acid;
  • Kolbe–Schmitt synthesis;
  • carbon dioxide;
  • organometallic reagents;
  • lactone;
  • pyrone;
  • C[BOND]C-coupling reactions;
  • carboxylation

Summary

This chapter contains sections titled:

  • Introduction

  • Formation of Aromatic Carboxylic Acids: The Kolbe–Schmitt Synthesis

  • Reactive Organometallic Derivatives in the Synthesis of Carboxylic Acids

  • Palladium (0)-Catalyzed Telomerization of Butadiene with CO2: Synthesis of δ-Lactone

  • References