Chapter 1. Catalysis Involving the H• Transfer Reactions of First-Row Transition Metals

  1. Dr. R. Morris Bullock
  1. John Hartung and
  2. Jack R. Norton

Published Online: 27 AUG 2010

DOI: 10.1002/9783527631582.ch1

Catalysis without Precious Metals

Catalysis without Precious Metals

How to Cite

Hartung, J. and Norton, J. R. (2010) Catalysis Involving the H• Transfer Reactions of First-Row Transition Metals, in Catalysis without Precious Metals (ed R. M. Bullock), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany. doi: 10.1002/9783527631582.ch1

Editor Information

  1. Pacific Northwest National Laboratory, Chemical and Materials Sciences Division, P.O. Box 999, K2-57, Richland, WA 99352, USA

Author Information

  1. Columbia University, Department of Chemistry, 3000 Broadway, New York, NY 10027, USA

Publication History

  1. Published Online: 27 AUG 2010
  2. Published Print: 8 SEP 2010

ISBN Information

Print ISBN: 9783527323548

Online ISBN: 9783527631582

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Keywords:

  • radical cyclization;
  • green;
  • hydrogen;
  • transition metal hydrides;
  • hydrogen atom transfer;
  • atom economy

Summary

This chapter contains sections titled:

  • H• Transfer Between M[BOND]H Bonds and Organic Radicals

  • H• Transfer Between Ligands and Organic Radicals

  • H• Transfer Between M[BOND]H and C[BOND]C Bonds

  • Chain Transfer Catalysis

  • Catalysis of Radical Cyclizations

  • Competing Methods for the Cyclization of Dienes

  • Summary and Conclusions

  • References