Chapter 3. Molybdenum and Tungsten Catalysts for Hydrogenation, Hydrosilylation and Hydrolysis

  1. Dr. R. Morris Bullock
  1. Dr. R. Morris Bullock

Published Online: 27 AUG 2010

DOI: 10.1002/9783527631582.ch3

Catalysis without Precious Metals

Catalysis without Precious Metals

How to Cite

Bullock, R. M. (2010) Molybdenum and Tungsten Catalysts for Hydrogenation, Hydrosilylation and Hydrolysis, in Catalysis without Precious Metals (ed R. M. Bullock), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany. doi: 10.1002/9783527631582.ch3

Editor Information

  1. Pacific Northwest National Laboratory, Chemical and Materials Sciences Division, P.O. Box 999, K2-57, Richland, WA 99352, USA

Author Information

  1. Pacific Northwest National Laboratory, Chemical and Materials Sciences Division, P.O. Box 999, K2-57, Richland, WA 99352, USA

Publication History

  1. Published Online: 27 AUG 2010
  2. Published Print: 8 SEP 2010

ISBN Information

Print ISBN: 9783527323548

Online ISBN: 9783527631582

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Keywords:

  • hydrogenation;
  • hydrosilylation;
  • molybdenum;
  • tungsten;
  • hydride transfer;
  • proton transfer

Summary

This chapter contains sections titled:

  • Introduction

  • Proton Transfer Reactions of Metal Hydrides

  • Hydride Transfer Reactions of Metal Hydrides

  • Stoichiometric Hydride Transfer Reactivity of Anionic Metal Hydride Complexes

  • Catalytic Hydrogenation of Ketones with Anionic Metal Hydrides

  • Ionic Hydrogenation of Ketones Using Metal Hydrides and Added Acid

  • Ionic Hydrogenations from Dihydrides: Delivery of the Proton and Hydride from One Metal

  • Catalytic Ionic Hydrogenations With Mo and W Catalysts

  • Mo Phosphine Catalysts With Improved Lifetimes

  • Tungsten Hydrogenation Catalysts with N-Heterocyclic Carbene Ligands

  • Catalysts for Hydrosilylation of Ketones

  • Cp2Mo Catalysts for Hydrolysis, Hydrogenations and Hydrations

  • Conclusion

  • Acknowledgements

  • References