7. Asymmetric Hydrogenation

  1. Prof. Dr. Piet W. N. M. van Leeuwen PhD1 and
  2. Dr. John C. Chadwick B.Sc., Ph.D.2

Published Online: 18 JUN 2011

DOI: 10.1002/9783527635993.ch7

Homogeneous Catalysts: Activity - Stability - Deactivation

Homogeneous Catalysts: Activity - Stability - Deactivation

How to Cite

van Leeuwen, P. W. N. M. and Chadwick, J. C. (2011) Asymmetric Hydrogenation, in Homogeneous Catalysts: Activity - Stability - Deactivation, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany. doi: 10.1002/9783527635993.ch7

Author Information

  1. 1

    Institute of Chemical Research of Catalonia (ICIQ), Av. Paisos Catalans 16, 43007 Tarragona, Spain

  2. 2

    University of Eindhoven, Chemical Engineering & Chemistry, P.O. Box 513, 5600 MB Eindhoven, The Netherlands

Publication History

  1. Published Online: 18 JUN 2011
  2. Published Print: 1 JUN 2011

ISBN Information

Print ISBN: 9783527323296

Online ISBN: 9783527635993

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Keywords:

  • incubation in hydrogenation catalysts;
  • substrate inhibition;
  • bridged dimers;
  • ligand decomposition;
  • product inhibition;
  • selective (de)activation of enantiomeric catalysts

Summary

This chapter contains sections titled:

  • Introduction

  • Incubation by Dienes in Rhodium Diene Precursors

  • Inhibition by Substrates, Solvents, Polar Additives, and Impurities

  • Inhibition by Formation of Bridged Species

  • Inhibition by Ligand Decomposition

  • Inhibition by the Product

  • Inhibition by Metal Formation; Heterogeneous Catalysis by Metals

  • Selective Activation and Deactivation of Enantiomeric Catalysts

  • Conclusions

  • References