18. Reactivity of Radicals toward Oxygen, Hydrogen Donors, Monomers, and Additives: Understanding and Discussion

  1. Prof. Jean Pierre Fouassier1 and
  2. Prof. Jacques Lalevée2

Published Online: 21 DEC 2012

DOI: 10.1002/9783527648245.ch18

Photoinitiators for Polymer Synthesis: Scope, Reactivity and Efficiency

Photoinitiators for Polymer Synthesis: Scope, Reactivity and Efficiency

How to Cite

Fouassier, J. P. and Lalevée, J. (2012) Reactivity of Radicals toward Oxygen, Hydrogen Donors, Monomers, and Additives: Understanding and Discussion, in Photoinitiators for Polymer Synthesis: Scope, Reactivity and Efficiency, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany. doi: 10.1002/9783527648245.ch18

Author Information

  1. 1

    formerly University of Haute Alsace, Ecole Nationale Supérieure de Chimie, 3 rue Alfred Werner, 68093 Mulhouse Cedex, France

  2. 2

    University of Haute Alsace, Institut Science des Matériaux, IS2M-LRC 7228, CNRS, 15 rue Jean Starcky, 68057 Mulhouse Cedex, France

Publication History

  1. Published Online: 21 DEC 2012
  2. Published Print: 4 JUL 2012

ISBN Information

Print ISBN: 9783527332106

Online ISBN: 9783527648245

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Keywords:

  • initiating radicals;
  • oxyls;
  • peroxyls;
  • reactivity;
  • hydrogen donors;
  • monomers;
  • kinetic data

Summary

This chapter contains sections titled:

  • Alkyl and Related Carbon-Centered Radicals

  • Aryl Radicals

  • Benzoyl Radicals

  • Acrylate and Methacrylate Radicals

  • Aminoalkyl Radicals

  • Phosphorus-Centered Radicals

  • Thiyl Radicals

  • Sulfonyl and Sulfonyloxy Radicals

  • Silyl Radicals

  • Oxyl Radicals

  • Peroxyl Radicals

  • Aminyl Radicals

  • Germyl and Stannyl Radicals

  • Boryl Radicals

  • Lophyl Radicals

  • Iminyl Radicals

  • Metal-Centered Radicals

  • Propagating Radicals

  • Radicals in Controlled Photopolymerization Reactions

  • Radicals in Hydrosilylation Reactions

  • References