7. Catalytic Rearrangements and Allylation Reactions in Water

  1. Prof. Dr. Pierre H. Dixneuf2,3 and
  2. Dr. Victorio Cadierno4
  1. Victorio Cadierno,
  2. Joaquín García-Álvarez and
  3. Sergio E. García-Garrido

Published Online: 4 JAN 2013

DOI: 10.1002/9783527656790.ch7

Metal-Catalyzed Reactions in Water

Metal-Catalyzed Reactions in Water

How to Cite

Cadierno, V., García-Álvarez, J. and García-Garrido, S. E. (2013) Catalytic Rearrangements and Allylation Reactions in Water, in Metal-Catalyzed Reactions in Water (eds P. H. Dixneuf and V. Cadierno), Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany. doi: 10.1002/9783527656790.ch7

Editor Information

  1. 2

    CNRS-Université de Rennes 1, Catalyse et Organométalliques, Campus de Beaulieu, Bat10c, 35042 Rennes Cedex, France

  2. 3

    UMR 6226: CNRS – Université de Rennes, Laboratoire “Organométalliques, Matériaux, Catalyse”, Institut Sciences Chimiques de Rennes, 35042 Rennes, France

  3. 4

    Universidad de Oviedo, Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica, “Enrique Moles” (Unidad Asociada al CSIC), Facultad de Química, Julían Clavería 8, 33006 Oviedo, Spain

Author Information

  1. Universidad de Oviedo, Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica, “Enrique Moles” (Unidad Asociada al CSIC), Facultad de Química, Julián Clavería 8, 33006 Oviedo, Spain

Publication History

  1. Published Online: 4 JAN 2013
  2. Published Print: 16 JAN 2013

ISBN Information

Print ISBN: 9783527331888

Online ISBN: 9783527656790

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Keywords:

  • rearrangement;
  • olefin isomerization;
  • redox isomerization;
  • cycloisomerization;
  • allylation of C=O and C=N bonds;
  • allylic substitution

Summary

Catalytic rearrangements, isomerizations, and allylation processes of organic substrates in aqueous media are reviewed. Enhanced or completely new reactivities in comparison with those processes performed in classical organic solvents are particularly highlighted.