Financial support from the Deutsche Forschungsgemeinschaft, the Fonds der Chemischen Industrie and the Bundesministerium für Bildung und Forschung is gratefully acknowledged. We thank H. Pernice and R. Ohlhof for their assistance in the quantitative analysis of the compounds studied.
Composites of Perylene Chromophores and Layered Double Hydroxides: Direct Synthesis, Characterization, and Photo- and Chemical Stability†
Article first published online: 7 MAR 2003
© 2003 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Advanced Functional Materials
Volume 13, Issue 3, pages 241–248, March, 2003
How to Cite
Bauer, J., Behrens, P., Speckbacher, M. and Langhals, H. (2003), Composites of Perylene Chromophores and Layered Double Hydroxides: Direct Synthesis, Characterization, and Photo- and Chemical Stability. Adv. Funct. Mater., 13: 241–248. doi: 10.1002/adfm.200390036
- Issue published online: 7 MAR 2003
- Article first published online: 7 MAR 2003
- Manuscript Accepted: 22 AUG 2002
- Manuscript Received: 5 JUN 2002
Composites of the tetra-anion of the perylene dye N,N′-di(phenyl-3,5-disulfonic acid)perylene-3,4:9,10-tetracarboxydiimide (PBITS) with layered double hydroxides (LDHs) were formed by direct synthesis (co-precipitation at constant pH). The LDHs were of the hydrotalcite (Mg–Al–OH and Zn–Al–OH compositions). During synthesis of the hydrocalumite type (Ca–Al–OH), partial destruction of the dye occurs, being more pronounced at higher pH values. The composites were characterized with regard to their composition by elemental and thermal analysis. From UV-vis spectroscopic data and powder X-ray diffraction, a structural model is developed for the composites. In the galleries between the hydroxide layers, the chromophore molecules are stacked in an J-type arrangement. The compounds have brilliant colors and are insoluble in common solvents. With regard to a possible application as pigments, their photostability and their chemical resistance against a typical application environment was tested. The photostability of the dye molecules and their chemical resistance against setting cement are slightly raised by the occlusion within the LDH structure; however, the photostability of the LDH–cement is lower than that of cement colored with the pure perylene dye.