Get access

Second Generation Nanostructured Metal Oxide Matrices to Increase the Thermal Stability of CO and NO2 Sensing Layers Based on Iron(II) Phthalocyanine


  • This work was financially supported by the Junta de Andalucia (Proyecto de Excelencia RMN-666). J.F.F.S. and I.F. thank the Junta de Andalucía for their research contracts and warmly thank Prof. P. S. Pregosin for helpful discussions and advice. Supporting Information is available online from Wiley InterScience or from the author.


An iron(II) phthalocyanine (FePc) complex solubilized by decylamine (DA) and benzylamine (BA) is incorporated into a nanoparticulate metal oxide matrix to develop optical sensor films sensitive to NO2 and CO. Eleven amine solvents have been tested as N-donor ligands that permit ligand exchange with the gas molecules. We have systematically investigated the suitability of different N-donor ligands, studied the thermal stability of the NO2- and CO-sensing films at 4, 25, 60, and 80 °C by photometry, and corroborated our findings by using NMR experiments. A satisfactory thermal stability of the films has not been obtained for chemically unmodified nanoparticulate metal oxide matrices. We have therefore developed a second generation of nanostructured metal oxide supports that show increased thermal stability and adequate sensitivity to NO2 and CO. These novel nanostructured matrices have been chemically modified using amines, alumina oligomers, and/or anti-gas-fading agents. These components have been integrated into the metal oxide matrices to avoid degradation of the optical films and to preserve their sensitivity.

Get access to the full text of this article