We thank the German Federal Ministry for Education and Research BMBF (network project 01SF0119) and the Deutsche Forschungsgemeinschaft (Leibniz prize) for financial support.
Organic Thin-Film Photovoltaic Cells Based on Oligothiophenes with Reduced Bandgap†
Article first published online: 31 AUG 2007
Copyright © 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Advanced Functional Materials
Volume 17, Issue 15, pages 2991–2999, October, 2007
How to Cite
Uhrich, C., Schueppel, R., Petrich, A., Pfeiffer, M., Leo, K., Brier, E., Kilickiran, P. and Baeuerle, P. (2007), Organic Thin-Film Photovoltaic Cells Based on Oligothiophenes with Reduced Bandgap. Adv. Funct. Mater., 17: 2991–2999. doi: 10.1002/adfm.200600917
- Issue published online: 11 OCT 2007
- Article first published online: 31 AUG 2007
- Manuscript Revised: 30 APR 2007
- Manuscript Received: 4 OCT 2006
- German Federal Ministry for Education and Research BMBF. Grant Number: 01SF0119
- Deutsche Forschungsgemeinschaft
- Photovoltaic devices;
The best polymeric solar cells reported so far are based on a so-called bulk heterojunction of a polythiophene as donor and a soluble fullerene derivative as acceptor. However, these cells still suffer from an unsatisfying photovoltage, typically below 0.7 V. Here, we show that we can achieve higher photovoltages using a new terthiophene end-capped with electron withdrawing dicyanovinyl groups (DCV3T) that increase both the ionization energy and even more strongly the electron affinity of the compound. The new material is tested in cells using a photoactive heterojunction to separate the excitons generated in the oligomer and a p-doped wide-gap transport layer. The solar cells show an open circuit voltage of up to 1.04 V and a broad spectral sensitivity band ranging from 420 nm to 650 nm. Solar cells based on such oligothiophenes are promising candidates for stacked organic solar cells tailored to the sun-spectrum. Moreover, we present first examples of a new concept for organic solar cells: By blending DCV3T with fullerene C60, an enhanced generation of triplet excitons on the oligomer can be achieved via a back and forth transfer of excitons (ping-pong-effect).