This work was supported by the RGC Research Grant Direct Allocation (Project Code: 2060332) and the NSFC/RGC Joint Research Scheme (Ref. No.: N_CUHK448/06, Project Code: 2900318). Supporting Information is available online from Wiley InterScience or from the authors.
Multifunctional Mesostructured Silica Microspheres from an Ultrasonic Aerosol Spray†
Article first published online: 22 SEP 2008
Copyright © 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Advanced Functional Materials
Volume 18, Issue 19, pages 2956–2962, October 9, 2008
How to Cite
Li, L., Tsung, C.-K., Ming, T., Sun, Z., Ni, W., Shi, Q., Stucky, G. D. and Wang, J. (2008), Multifunctional Mesostructured Silica Microspheres from an Ultrasonic Aerosol Spray. Adv. Funct. Mater., 18: 2956–2962. doi: 10.1002/adfm.200800453
- Issue published online: 6 OCT 2008
- Article first published online: 22 SEP 2008
- Manuscript Revised: 29 MAY 2008
- Manuscript Received: 1 APR 2008
- multifunctional microspheres;
- photoacid generators;
- rare-earth complexes;
Multifunctional mesostructured silica microspheres are prepared using ultrasonic aerosol spray in conjunction with solvent evaporation-induced assembly. Rare earth ion–phenanthroline complexes, magnetite particles, photoacid generators, and pH-sensitive dyes are chosen as luminescent, magnetic, and photosensitive components. The incorporation of these functional components into mesostructured silica microspheres can be readily realized by dispersing them in the precursor solution of the aerosol spray process. Luminescent microspheres that can emit at multiple wavelengths when excited at a single wavelength are produced by the addition of multiple rare earth complexes into the precursor solution. The addition of magnetite particles leads to the production of magnetic luminescent microspheres. Photoacid generators and pH-sensitive dyes are further employed to produce magnetic photosensitive microspheres that can release acid and change color upon UV light illumination. Such multifunctional microspheres could have exciting potential for many optical and biotechnological applications, such as multiplexed labeling, diagnosis, simultaneous imaging and therapy, cell capture and separation, targeted delivery, and optical data storage.