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Three-Dimensional Co3O4@MnO2 Hierarchical Nanoneedle Arrays: Morphology Control and Electrochemical Energy Storage

Authors

  • Dezhi Kong,

    1. Shanghai Key Laboratory of Special Artificial, Microstructure Materials and Technology, School of Physics Science and Engineering, Tongji University, Shanghai, P. R. China
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  • Jingshan Luo,

    1. Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore
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  • Yanlong Wang,

    1. Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore
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  • Weina Ren,

    1. Shanghai Key Laboratory of Special Artificial, Microstructure Materials and Technology, School of Physics Science and Engineering, Tongji University, Shanghai, P. R. China
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  • Ting Yu,

    1. Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore
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  • Yongsong Luo,

    1. Department of Physics & Electronic Engineering, Xinyang Normal University, Xinyang, P. R. China
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  • Yaping Yang,

    1. Shanghai Key Laboratory of Special Artificial, Microstructure Materials and Technology, School of Physics Science and Engineering, Tongji University, Shanghai, P. R. China
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  • Chuanwei Cheng

    Corresponding author
    1. Shanghai Key Laboratory of Special Artificial, Microstructure Materials and Technology, School of Physics Science and Engineering, Tongji University, Shanghai, P. R. China
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Abstract

In this paper, a highly ordered three-dimensional Co3O4@MnO2 hierarchical porous nanoneedle array on nickel foam is fabricated by a facile, stepwise hydrothermal approach. The morphologies evolution of Co3O4 and Co3O4@MnO2 nanostructures upon reaction times and growth temperature are investigated in detail. Moreover, the as-prepared Co3O4@MnO2 hierarchical structures are investigated as anodes for both supercapacitors and Li-ion batteries. When used for supercapacitors, excellent electrochemical performances such as high specific capacitances of 932.8 F g−1 at a scan rate of 10 mV s−1 and 1693.2 F g−1 at a current density of 1 A g−1 as well as long-term cycling stability and high energy density (66.2 W h kg−1 at a power density of 0.25 kW kg−1), which are better than that of the individual component of Co3O4 nanoneedles and MnO2 nanosheets, are obtained. The Co3O4@MnO2 NAs are also tested as anode material for LIBs for the first time, which presents an improved performance with high reversible capacity of 1060 mA h g−1 at a rate of 120 mA g−1, good cycling stability, and rate capability.

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