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Magnetic properties of polyoxovanadates: Magnetic confirmation of the valence state of the vanadium centers in Na6[H6 V12O30F2] · 22H2O†
Article first published online: 29 OCT 2004
Copyright © 1993 Verlag GmbH & Co. KGaA, Weinheim
Volume 5, Issue 12, pages 915–917, December 1993
How to Cite
Müller, A., Rohlfing, R., Barra, A.-L. and Gatteschi, D. (1993), Magnetic properties of polyoxovanadates: Magnetic confirmation of the valence state of the vanadium centers in Na6[H6 V12O30F2] · 22H2O. Adv. Mater., 5: 915–917. doi: 10.1002/adma.19930051207
- Issue published online: 29 OCT 2004
- Article first published online: 29 OCT 2004
- Manuscript Received: 9 AUG 1993
Oxovanadium clusters are intersting both as moels of bulk magnets and in their own right. Results are presented suggesting that in Na6[H6V12O30F2]·22H2O (see Figure) it is meaningful to decide which particular vanadium centers should be considered at 5⊕ and which as 4⊕. It is shown that in principle ist is possible to tune and design the topology, and thus the magnetic properties, of polyoxovanadates(IV/V) by means of the template effect.