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Synthesis, crystal structure, magnetic properties, and spin densities of a triazole-nitronyl-nitroxide radical

Authors

  • Dr. Yu Pei,

    Corresponding author
    1. Laboratoire de Chimie Inorganique, URA CNRS no. 420 Université de Paris Sud, F-91405 Orsay (France)
    • Laboratoire de Chimie Inorganique, URA CNRS no. 420 Université de Paris Sud, F-91405 Orsay (France)
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  • Prof. Olivier Kahn,

    1. Laboratoire de Chimie Inorganique, URA CNRS no. 420 Université de Paris Sud, F-91405 Orsay (France)
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  • Dr. Michael A. Aebersold,

    1. Laboratoire de Chimie Inorganique, URA CNRS no. 420 Université de Paris Sud, F-91405 Orsay (France)
    2. Laboratoire Léon Brillouin, Centre d'Etudes Nucléaires de Saclay F-91191 Gif-sur-Yvette (France)
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  • Dr. Lahcène Ouahab,

    1. Laboratoire de Chimie du Solide et Inorganique Moléculaire URA CNRS no. 1495, Université de Rennes 1 F-35042 Rennes (France)
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  • Françoise Le Berre,

    1. Laboratoire de Chimie du Solide et Inorganique Moléculaire URA CNRS no. 1495, Université de Rennes 1 F-35042 Rennes (France)
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  • Dr. Luca Pardi,

    1. Laboratoire Léon Brillouin, Centre d'Etudes Nucléaires de Saclay F-91191 Gif-sur-Yvette (France)
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  • Dr. Jean Louis Tholence

    1. Centre de Recherche sur les Très Basses Températures UPR CNRS no. 5001 F-38042 Grenoble (France)
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Abstract

A triazole-nitronyl-nitroxide radical (see Figure) combining a 1,2,4-triazole function—which plays an important role in the field of spin transition compounds—and a nitronyl nitroxide radical— a magnetic building blick used in organic magnets — is reported. Its synthesis, crystyal structure, magnetic properties and spin densities are described.

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