Also at the Department of Chemistry.
Magnetic field induced reversed (Negative) magnetization for electrochemically deposited Tc = 260 K Oxidized Films of Chromium Cyanide Magnets†
Article first published online: 29 OCT 2004
Copyright © 1997 Verlag GmbH & Co. KGaA, Weinheim
Volume 9, Issue 8, pages 645–647, Juli 1997
How to Cite
Buschmann, W. E., Paulson, S. C., Wynn, C. M., Girtu, M. A., Epstein, A. J., White, H. S. and Miller, J. S. (1997), Magnetic field induced reversed (Negative) magnetization for electrochemically deposited Tc = 260 K Oxidized Films of Chromium Cyanide Magnets. Adv. Mater., 9: 645–647. doi: 10.1002/adma.19970090812
We gratefully acknowledge support from the US National Science Foundation, Grant no. CHE-9320478, Department of Energy, Division of Materials Science, Grant no. DE-FG02-86ER45271.A000, Department of Energy, Division of Advanced Energy Projects, Grant no. DE-FG02-96ER12198, and the Office of Naval Research.
- Issue published online: 29 OCT 2004
- Article first published online: 29 OCT 2004
- Manuscript Revised: 10 MAR 1997
- Manuscript Received: 4 FEB 1997
Molecule-based magnets with high ordering temperaturesTc (above room temperature) include some mixed-oxide hexacyanometallates. The example studied here, Cr2.12(CN)6 · ½ H2O (the Figure shows its crystalline and amorphous phases), is shown to have Tc equals; 260 K and exhibit negative (reverse) magnetization. An explanation is suggested for this behavior and the temperature and field dependences of the magnetization.