The authors gratefully acknowledge Prof. Dr. L. W. Jenneskens and Dr. C. A. van Walree (UU) for the use of the CARY 5 spectrophotometer. This work is part of the research program of the “Stichting voor Fundamenteel Onderzoek der Materie (FOM)”, which is financially supported by the “Nederlandse organisatie voor Wetenschappelijk Onderzoek (NWO)”. J. J. Penninkhof and C. Graf contributed equally to the work.
Communication
Angle-Dependent Extinction of Anisotropic Silica/Au Core/Shell Colloids Made via Ion Irradiation†
Article first published online: 7 JUN 2005
DOI: 10.1002/adma.200401742
Copyright © 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Penninkhof, J. J., Graf, C., van Dillen, T., Vredenberg, A. M., van Blaaderen, A. and Polman, A. (2005), Angle-Dependent Extinction of Anisotropic Silica/Au Core/Shell Colloids Made via Ion Irradiation. Adv. Mater., 17: 1484–1488. doi: 10.1002/adma.200401742
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Publication History
- Issue published online: 7 JUN 2005
- Article first published online: 7 JUN 2005
- Manuscript Accepted: 17 FEB 2005
- Manuscript Received: 22 OCT 2004
Correction: Angle-Dependent Extinction of Anisotropic Silica/Au Core/Shell Colloids Made via Ion Irradiation
Vol. 18, Issue 21, 2802, Article first published online: 30 OCT 2006
- Abstract
- References
- Cited By
Keywords:
- Core–shell particles;
- Photonic materials

Spherical colloids with silica cores (300–500 nm diameter) and gold shells (20–60 nm thickness) are shown to deform to form oblate ellipsoids under ion-beam irradiation, as shown in the Figure. The deformation, which can be controlled by ion fluence, is attributed to an ion-induced anisotropic deformation in the amorphous silica that is constrained mechanically by the gold shell. The optical extinction of these samples is highly angle-dependent.

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