This research was supported by NSFC Nos. 20343001, 20473095, CMS-CX2003, SRF for ROCS, SEM, China and the CNRS, France.
Tetrathiafulvalene [FeIII(C2O4)Cl2]: An Organic–Inorganic Hybrid Exhibiting Canted Antiferromagnetism†
Article first published online: 4 AUG 2005
Copyright © 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Volume 17, Issue 16, pages 1988–1991, August, 2005
How to Cite
Zhang, B., Wang, Z., Fujiwara, H., Kobayashi, H., Kurmoo, M., Inoue, K., Mori, T., Gao, S., Zhang, Y. and Zhu, D. (2005), Tetrathiafulvalene [FeIII(C2O4)Cl2]: An Organic–Inorganic Hybrid Exhibiting Canted Antiferromagnetism. Adv. Mater., 17: 1988–1991. doi: 10.1002/adma.200500766
- Issue published online: 4 AUG 2005
- Article first published online: 4 AUG 2005
- Manuscript Accepted: 10 MAY 2005
- Manuscript Received: 15 APR 2005
- Hybrid materials, organic–inorganic;
- Magnetic materials;
A new organic–inorganic hybrid, (TTF+)FeIII(C2O4)Cl2, displaying canted antiferromagnetism has been prepared and characterized, where the tetrathiafulvalene (TTF) molecules are face-to-face dimers and the anion is a one-dimensional coordination polymer (see Figure). Due to π–d interactions through short S…Cl and S…O contacts a three-dimensional Néel state is stabilized at the high temperature of 20 K.