Advanced Materials

A Highly Porous Luminescent Terbium–Organic Framework for Reversible Anion Sensing

Authors


  • The authors acknowledge the financial support of the Hong Kong Research Grants Council, The University of Hong Kong, and the National Natural Science Foundation of China (50572125). K.L.W. and G.L.L. acknowledge the receipt of a postgraduate studentship administered by The University of Hong Kong. Supporting Information is available online from Wiley InterScience or from the author.

Abstract

Unique tailored porous frameworks incorporating a lanthanide metal center have been designed to function as chemical detectors. A flexible multidentate ligand, mucic acid, is used to differentiate between several anions, thus creating an organic framework (see figure) that is ideally suited for applications in gas separation, sensors, and chemical switches.

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