This work was supported by the NSF grants DMR-0405208 and ECS-0437932. Supporting Information is available online from Wiley InterScience or from the author.
Communication
Nanoscale Surface Morphology and Rectifying Behavior of a Bulk Single-Crystal Organic Semiconductor†
Article first published online: 18 MAY 2006
DOI: 10.1002/adma.200502569
Copyright © 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Menard, E., Marchenko, A., Podzorov, V., Gershenson, M., Fichou, D. and Rogers, J. (2006), Nanoscale Surface Morphology and Rectifying Behavior of a Bulk Single-Crystal Organic Semiconductor. Advanced Materials, 18: 1552–1556. doi: 10.1002/adma.200502569
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Publication History
- Issue published online: 20 JUN 2006
- Article first published online: 18 MAY 2006
- Manuscript Accepted: 8 MAR 2006
- Manuscript Received: 30 NOV 2005
Keywords:
- Charge transport;
- Semiconductors, organic;
- Single crystals
Graphical Abstract

Local surface measurements of rubrene single crystals reveal interesting insights on carrier transport mechanisms at the active interface of high-performance field-effect “air-gap stamp” transistors. Scanning tunnelling microscopy (STM) images, combined with atomic force microscopy and X-ray diffraction, reveal directly the position and orientation of individual molecules in the a–b plane (see figure and inside cover). Local current–voltage curves recorded using STM in the dark and under light indicate a rectifying p-type behavior.

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