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Advanced Materials

Cookie-like Au/NiO Nanoparticles with Optical Gas-Sensing Properties


  • This work was supported by the Ministero Dell'Università e della Ricerca Scientifica (MURST) within a “Progetto di Ateneo n. CPDA042175” project of Padova University.


Cookie-like Au/NiO nanoparticles are grown inside a porous SiO2 sol–gel film (see figure). High-resolution TEM measurements reveal a twofold structure of the nanoparticles, showing a sharp interface with epitaxial coherence of the two phases. The nanocomposite films show a reversible change in optical absorbance in the vis-NIR wavelength range when exposed to carbon monoxide.

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