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Ice-Templating of Core/Shell Microgel Fibers through ‘Bricks-and-Mortar’ Assembly**


  • This work made use of MRL Central Facilities supported by the MRSEC Program of the National Science Foundation under award No. DMR05-20415. QS and HL acknowledge financial support from the UC Discovery Grant program and Genencor International. CKT acknowledges financial support from the National Science Foundation under Award No. DMR 02-33728. ZA acknowledges financial support from the Mitsubishi Chemical Center for Advanced Materials. Supporting Information is available online from Wiley InterScience or from the author.


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A ‘bricks-and-mortar’ assembly approach can be used to create well- defined fibers on the microscale with alternating organic-inorganic arrangement through a simple ice-templating strategy. The fibers are constructed from closely packed monodisperse inorganic nanoparticles@PNIPAm core/shell microgels. A series of functional ‘bricks’, such as core/shell and hollow nanoparticles are prepared.

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