The authors are indebted to the Max Planck Society and acknowledge support within the framework of the ENERCHEM project. The authors would like to acknowledge technical assistance from the Combicat Centre, Universiti Malaya (Kuala Lumpur, Malaysia); Edith Kitzelmann, Fritz-Haber-Institut; and Dr. Andreja Gajović, Molecular Physics Laboratory, Rudjer Boskovic Institute (Zagred, Croatia). Supporting Information is available online from Wiley InterScience or from the author.
Communication
CNFs@CNTs: Superior Carbon for Electrochemical Energy Storage†
Article first published online: 28 MAR 2008
DOI: 10.1002/adma.200701685
Copyright © 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Zhang, J., Hu, Y.-S., Tessonnier, J.-P., Weinberg, G., Maier, J., Schlögl, R. and Su, D. S. (2008), CNFs@CNTs: Superior Carbon for Electrochemical Energy Storage. Advanced Materials, 20: 1450–1455. doi: 10.1002/adma.200701685
- †
Publication History
- Issue published online: 21 APR 2008
- Article first published online: 28 MAR 2008
- Manuscript Revised: 20 AUG 2007
- Manuscript Received: 11 JUL 2007
Keywords:
- carbon nanotubes;
- carbon nanofibers;
- electrochemical energy storage;
- carbon hybrids
Graphical Abstract

Carbon-nanotube-encapsulated carbon nanofibers (CNFs@CNTs) with a novel one-dimensional structure are synthesized via the selective assembly of CNFs inside the channels of CNTs (see figure). The resulting novel carbon hybrid material serves as stable anode in lithium batteries during 120 charge/discharge cycles. This work provides a simple and efficient way of converting conventional CNTs into functional carbon materials with an outstandingly high volumetric storage density.

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