Synthesis of Hierarchically Structured Metal Oxides and their Application in Heavy Metal Ion Removal

Authors

  • Jin-Song Hu,

    1. Beijing National Laboratory for Molecular Sciences (BNLMS), and Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 (P. R. China)
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  • Liang-Shu Zhong,

    1. Beijing National Laboratory for Molecular Sciences (BNLMS), and Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 (P. R. China)
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  • Wei-Guo Song,

    Corresponding author
    1. Beijing National Laboratory for Molecular Sciences (BNLMS), and Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 (P. R. China)
    • Beijing National Laboratory for Molecular Sciences (BNLMS), and Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 (P. R. China).
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  • Li-Jun Wan

    Corresponding author
    1. Beijing National Laboratory for Molecular Sciences (BNLMS), and Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 (P. R. China)
    • Beijing National Laboratory for Molecular Sciences (BNLMS), and Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 (P. R. China).
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  • Funding from the National Natural Science Foundation of China (NSFC 20673125, 20733004, 20673121, 20603041, and 50725207), Ministry of Science and Technology (MOST 2007CB936403 and 2006CB806100), and the Chinese Academy of Sciences is gratefully acknowledged. The authors thank Professor Chun-Li Bai for valuable advice.

Abstract

Hierarchically structured metal oxides have two or more levels of structure. Their nanometer-sized building blocks provide a high surface area, a high surface-to-bulk ratio, and surface functional groups that can interact with, e.g., heavy metal ions. Their overall micrometer-sized structure provides desirable mechanical properties, such as robustness, facile species transportation, easy recovery, and regeneration. In combination these features are suitable for the removal of heavy metal ions from water. Several general synthesis routes for the fabrication of metal oxides with various morphologies and hierarchical structures are discussed including soft and hard template-assisted routes. These routes are general, reliable, and environmentally friendly methods to prepare transition and rare earth metal oxides, including cobalt oxide, iron oxide, and ceria. As-prepared hierarchically structured metal oxides show excellent adsorption capacities for AsV and CrVI ions in water.

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