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A Graphene Hybrid Material Covalently Functionalized with Porphyrin: Synthesis and Optical Limiting Property

Authors

  • Yanfei Xu,

    1. Key Laboratory for Functional Polymer Materials and Centre for Nanoscale Science and Technology Institute of Polymer Chemistry College of Chemistry Nankai University, Tianjin 300071 (P.R. China)
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  • Zhibo Liu,

    1. Key Laboratory of Weak Light Non-linear Photonics Ministry of Education and Teda Applied Physics School Nankai University, Tianjin 300457 (P.R. China)
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  • Xiaoliang Zhang,

    1. Key Laboratory of Weak Light Non-linear Photonics Ministry of Education and Teda Applied Physics School Nankai University, Tianjin 300457 (P.R. China)
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  • Yan Wang,

    1. Key Laboratory for Functional Polymer Materials and Centre for Nanoscale Science and Technology Institute of Polymer Chemistry College of Chemistry Nankai University, Tianjin 300071 (P.R. China)
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  • Jianguo Tian,

    Corresponding author
    1. Key Laboratory of Weak Light Non-linear Photonics Ministry of Education and Teda Applied Physics School Nankai University, Tianjin 300457 (P.R. China)
    • Key Laboratory of Weak Light Non-linear Photonics Ministry of Education and Teda Applied Physics School Nankai University, Tianjin 300457 (P.R. China).
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  • Yi Huang,

    1. Key Laboratory for Functional Polymer Materials and Centre for Nanoscale Science and Technology Institute of Polymer Chemistry College of Chemistry Nankai University, Tianjin 300071 (P.R. China)
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  • Yanfeng Ma,

    1. Key Laboratory for Functional Polymer Materials and Centre for Nanoscale Science and Technology Institute of Polymer Chemistry College of Chemistry Nankai University, Tianjin 300071 (P.R. China)
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  • Xiaoyan Zhang,

    1. Key Laboratory for Functional Polymer Materials and Centre for Nanoscale Science and Technology Institute of Polymer Chemistry College of Chemistry Nankai University, Tianjin 300071 (P.R. China)
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  • Yongsheng Chen

    Corresponding author
    1. Key Laboratory for Functional Polymer Materials and Centre for Nanoscale Science and Technology Institute of Polymer Chemistry College of Chemistry Nankai University, Tianjin 300071 (P.R. China)
    • Key Laboratory for Functional Polymer Materials and Centre for Nanoscale Science and Technology Institute of Polymer Chemistry College of Chemistry Nankai University, Tianjin 300071 (P.R. China).
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Abstract

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An organic solution-processable functionalized graphene (SPFGraphene) hybrid material with porphyrins is reported for the first time. FTIR, UV-vis absorption, and TEM studies confirm the covalent functionalization of the graphene. A superior optical limiting effect, better than the benchmark optical limiting material C60 and the control sample, is observed.

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