Advanced Materials

Calamitic Liquid-Crystalline Elastomers Swollen in Bent-Core Liquid-Crystal Solvents



The swelling of calamitic liquid crystal elastomers (LCEs) with bent-core mesogens is investigated in the isotropic phase of both materials. The swelling magnitude and dynamics are determined and fitted with a dual exponential. The host LCEs imbibe bent-core molecules up to 30– 40 mol%. The swollen elastomers exhibit nematic phases, with some possessing a lower temperature smectic phase.

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