A novel thiophene-thienylenevinylene copolymer is synthesized and evaluated for use in organic field-effect transistors and organic solar cells. PETV12T shows good solution processability and high structural organization after annealing. Organic thin-film transistors based on the polymer exhibit high mobility and a high resistance to oxidation. In addition, PETV12T shows potential as an electron donor in bulk heterojunction solar cells.
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