An effective O2-reducing bioelectrocatalytic electrode is prepared by the electrochemical crosslinking of thioaniline-modified Pt nanoparticles (NPs) and thioaniline-functionalized bilirubin oxidase (BOD). An O2/ethanol biofuel cell element is constructed by integrating the Pt NP/BOD cathode and an electrically contacted alcohol dehydrogenase (AlcDH)-based anode.
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