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Advanced Materials

Pore Surface Tailored SOD-Type Metal-Organic Zeolites

Authors

  • Jie-Peng Zhang,

    Corresponding author
    1. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
    • MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.
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  • Ai-Xin Zhu,

    1. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
    2. School of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650092, China
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  • Rui-Biao Lin,

    1. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
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  • Xiao-Lin Qi,

    1. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
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  • Xiao-Ming Chen

    1. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
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Abstract

Replacing the organic linker in sodalite-type zinc 2-methylimidazolate by 3-methyl-1,2,4-triazolate produces isomorphous pure triazolate or solid solution imidazolate/triazolate frameworks functionalized by uncoordinated nitrogen donors. These show dramatically enhanced and fine-tuned sorption performance for practical adsorptive applications.

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