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The Potential of Molecular Self-Assembled Monolayers in Organic Electronic Devices

Authors

  • Marcus Halik,

    Corresponding author
    1. Organic Materials and Devices, Institute of Polymer Materials, University of Erlangen–Nürnberg, Martensstrasse 07, 91058 Erlangen, Germany
    • Organic Materials and Devices, Institute of Polymer Materials, University of Erlangen–Nürnberg, Martensstrasse 07, 91058 Erlangen, Germany.
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  • Andreas Hirsch

    1. Institute for Organic Chemistry II, University of Erlangen–Nürnberg, Henkestrasse 42, 91054 Erlangen, Germany
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Abstract

Functionalized molecules that organize to self-assembled monolayers (SAMs) are gaining importance in organic electronic devices. They are fully compatible with flexible substrates, are amenable to low-cost processing, and show reliable film-forming behavior. Highly integrated devices, such as sensor arrays or memories, have also been demonstrated. Starting from auxiliary layers, which improve and modify surfaces and interfaces in traditional thin-film devices, the applications of SAMs develop towards molecular scale electronics, including active molecular device layers and multifunctional SAMs, which fulfill several layer functions of a device within one monolayer. Mixed SAMs make new and tunable device features possible, by stoichiometric control of the composition of different SAM-forming molecules.

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