Communication
Controlling Reversible Dielectric Breakdown in Metal/Polymer Nanocomposites
Article first published online: 7 MAR 2012
DOI: 10.1002/adma.201104334
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Kim, J. and Grzybowski, B. A. (2012), Controlling Reversible Dielectric Breakdown in Metal/Polymer Nanocomposites. Adv. Mater., 24: 1850–1855. doi: 10.1002/adma.201104334
Publication History
- Issue published online: 4 APR 2012
- Article first published online: 7 MAR 2012
- Manuscript Received: 11 NOV 2011
- Abstract
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- References
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Keywords:
- nanocomposites;
- metals;
- polymers;
- electrical breakdown;
- bistability

Composites comprising metal nanorods encased in a polymer matrix exhibit reversible electric breakdown and can be cycled between low- and high-conductance states multiple times without permanent damage to the material. The voltage at which the breakdown occurs can be adjusted by engineering the properties of the polymeric matrix, in particular by doping the polymer with dipole-possessing additives whose role is to screen the applied electric fields.

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