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Binary and Ternary Atomic Layers Built from Carbon, Boron, and Nitrogen

Authors

  • Li Song,

    1. Department of Mechanical Engineering & Materials Science, Rice University, Houston Texas 77005, USA
    Current affiliation:
    1. Research Center for Exotic Nanocarbons, Shinshu University, 4-17-1Wakasato, Nagano 380-8553, Japan
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  • Zheng Liu,

    1. Department of Mechanical Engineering & Materials Science, Rice University, Houston Texas 77005, USA
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  • Arava Leela Mohana Reddy,

    1. Department of Mechanical Engineering & Materials Science, Rice University, Houston Texas 77005, USA
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  • Narayanan Tharangattu Narayanan,

    1. Department of Mechanical Engineering & Materials Science, Rice University, Houston Texas 77005, USA
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  • Jaime Taha-Tijerina,

    1. Department of Mechanical Engineering & Materials Science, Rice University, Houston Texas 77005, USA
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  • Juan Peng,

    1. Department of Mechanical Engineering & Materials Science, Rice University, Houston Texas 77005, USA
    Current affiliation:
    1. Key Laboratory of Energy Sources and Chemical Engineering, School of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, P. R. China
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  • Guanhui Gao,

    1. Department of Mechanical Engineering & Materials Science, Rice University, Houston Texas 77005, USA
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  • Jun Lou,

    1. Department of Mechanical Engineering & Materials Science, Rice University, Houston Texas 77005, USA
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  • Robert Vajtai,

    1. Department of Mechanical Engineering & Materials Science, Rice University, Houston Texas 77005, USA
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  • Pulickel M. Ajayan

    Corresponding author
    1. Department of Mechanical Engineering & Materials Science, Rice University, Houston Texas 77005, USA
    • Department of Mechanical Engineering & Materials Science, Rice University, Houston Texas 77005, USA.
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Abstract

Two-dimensional (2D) atomic layers derived from bulk layered materials are very interesting from both scientific and application viewpoints, as evidenced from the story of graphene. Atomic layers of several such materials such as hexagonal boron nitride (h-BN) and dichalcogenides are examples that complement graphene. The observed unconventional properties of graphene has triggered interest in doping the hexagonal honeycomb lattice of graphene with atoms such as boron (B) and nitrogen (N) to obtain new layered structures. Individual atomic layers containing B, C, and N of various compositions conform to several stable phases in the three-component phase diagram of B–C–N. Additionally, stacking layers built from C and BN allows for the engineering of new van-der-Waals stacked materials with novel properties. In this paper, the synthesis, characterization, and properties of atomically thin layers, containing B, C, and N, as well as vertically assembled graphene/h-BN stacks are reviewed. The electrical, mechanical, and optical properties of graphene, h-BN, and their hybrid structure are also discussed along with the applications of such materials.

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