Highly Selective Chemical Sensing in a Luminescent Nanoporous Magnet

Authors

  • Jesús Ferrando-Soria,

    1. Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna 46980, València, Spain
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  • Hossein Khajavi,

    1. Catalysis Engineering-Chemical Engineering Dept, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands
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  • Pablo Serra-Crespo,

    1. Catalysis Engineering-Chemical Engineering Dept, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands
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  • Jorge Gascon,

    Corresponding author
    1. Catalysis Engineering-Chemical Engineering Dept, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands
    • Catalysis Engineering-Chemical Engineering Dept, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands
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  • Freek Kapteijn,

    1. Catalysis Engineering-Chemical Engineering Dept, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands
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  • Miguel Julve,

    1. Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna 46980, València, Spain
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  • Francesc Lloret,

    Corresponding author
    1. Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna 46980, València, Spain
    • Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna 46980, València, Spain.
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  • Jorge Pasán,

    1. Laboratorio de Rayos X y Materiales Moleculares, Departamento de Física Fundamental II, Universidad de La Laguna, La Laguna 38201, Tenerife, Spain
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  • Catalina Ruiz-Pérez,

    1. Laboratorio de Rayos X y Materiales Moleculares, Departamento de Física Fundamental II, Universidad de La Laguna, La Laguna 38201, Tenerife, Spain
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  • Yves Journaux,

    1. Institut Parisien de Chimie Moléculaire, Université Pierre et Marie Curie-Paris6, UMR 7071, Paris 75252, France
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  • Emilio Pardo

    Corresponding author
    1. Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna 46980, València, Spain
    • Instituto de Ciencia Molecular (ICMOL), Universitat de València, Paterna 46980, València, Spain.
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Abstract

original image

On the road to chemical sensors: A novel 2D oxamato-based manganese(II)-copper(II) mixed-metal–organic framework (M'MOF) exhibiting non-linear fluorescence and long-range magnetic ordering is reported. This new luminescent nanoporous magnet features highly selective solvent- and gas sorption-induced optical switching behavior, opening the door to potential application for sensing of small molecules.

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