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Advanced Materials

Self-Healing Polymer Coatings Based on Crosslinked Metallosupramolecular Copolymers

Authors

  • Stefan Bode,

    1. Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich-Schiller-University Jena, Humboldtstr. 10, 07743 Jena, Germany
    2. Jena Center for Soft Matter (JCSM), Friedrich-Schiller-University Jena, Philosophenweg 7, 07743 Jena, Germany
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  • Linda Zedler,

    1. Jena Center for Soft Matter (JCSM), Friedrich-Schiller-University Jena, Philosophenweg 7, 07743 Jena, Germany
    2. Institute of Physical Chemistry (IPC) and Abbe Center of Photonics (ACP), Friedrich-Schiller-University Jena, Helmholtzweg 4, 07743 Jena, Germany
    3. Institute of Photonic Technology (IPHT) Jena, Albert-Einstein-Straße 9, 07745 Jena, Germany
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  • Felix H. Schacher,

    1. Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich-Schiller-University Jena, Humboldtstr. 10, 07743 Jena, Germany
    2. Jena Center for Soft Matter (JCSM), Friedrich-Schiller-University Jena, Philosophenweg 7, 07743 Jena, Germany
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  • Benjamin Dietzek,

    1. Jena Center for Soft Matter (JCSM), Friedrich-Schiller-University Jena, Philosophenweg 7, 07743 Jena, Germany
    2. Institute of Physical Chemistry (IPC) and Abbe Center of Photonics (ACP), Friedrich-Schiller-University Jena, Helmholtzweg 4, 07743 Jena, Germany
    3. Institute of Photonic Technology (IPHT) Jena, Albert-Einstein-Straße 9, 07745 Jena, Germany
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  • Michael Schmitt,

    1. Jena Center for Soft Matter (JCSM), Friedrich-Schiller-University Jena, Philosophenweg 7, 07743 Jena, Germany
    2. Institute of Physical Chemistry (IPC) and Abbe Center of Photonics (ACP), Friedrich-Schiller-University Jena, Helmholtzweg 4, 07743 Jena, Germany
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  • Jürgen Popp,

    1. Jena Center for Soft Matter (JCSM), Friedrich-Schiller-University Jena, Philosophenweg 7, 07743 Jena, Germany
    2. Institute of Physical Chemistry (IPC) and Abbe Center of Photonics (ACP), Friedrich-Schiller-University Jena, Helmholtzweg 4, 07743 Jena, Germany
    3. Institute of Photonic Technology (IPHT) Jena, Albert-Einstein-Straße 9, 07745 Jena, Germany
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  • Martin D. Hager,

    Corresponding author
    1. Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich-Schiller-University Jena, Humboldtstr. 10, 07743 Jena, Germany
    2. Jena Center for Soft Matter (JCSM), Friedrich-Schiller-University Jena, Philosophenweg 7, 07743 Jena, Germany
    • Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich-Schiller-University Jena, Humboldtstr. 10, 07743 Jena, Germany.
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  • Ulrich S. Schubert

    Corresponding author
    1. Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich-Schiller-University Jena, Humboldtstr. 10, 07743 Jena, Germany
    2. Jena Center for Soft Matter (JCSM), Friedrich-Schiller-University Jena, Philosophenweg 7, 07743 Jena, Germany
    3. Dutch Polymer Institute (DPI), 5600 AX Eindhoven, The Netherlands
    • Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich-Schiller-University Jena, Humboldtstr. 10, 07743 Jena, Germany.
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Abstract

Self-healing coating based on metallopolymers are prepared and fully characterized. Iron bisterpyridine complexes are incorporated into a polymer network based on methacrylates, resulting in self-healing properties of these materials. Moreover, the influence of the comonomers on the thermal properties is studied in detail.

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