Optoelectronic Devices: Large Photovoltages Generated by Plant Photosystem I Crystals (Adv. Mater. 22/2012)



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N. Nelson and co-workers describe on page 2988 micrometre-thick plant photosystem I crystals of up to 1000 layers of serially arranged protein chlorophyll complexes. In these proteins, photosynthesis efficiently converts light to electricity, generating unprecedented photovoltages (>49 V). The crystals are self-assembled from nanometre-sized protein structures. The successive layers form serially photoinduced dipoles in the crystal that give rise to a large electric field. The millimetre-size crystals are stable, function in a dry environment, and can be used in micro-optoelectronic devices.