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Keywords:

  • gas adsorption;
  • heterocycle;
  • microporous polymer;
  • selectivity
Thumbnail image of graphical abstract

On page 5703, Bien Tan and co-workers demonstrate an easy and straightforward route for the preparation of aromatic heterocycle-based microporous organic polymers. Owing to the narrow pore system and the heteroatom-rich pore surface, these networks exhibit large CO2 adsorption capacity and high selectivity toward CO2/N2. The frontispiece shows the density map of the adsorbed CO2 molecules in the simulated microporous structure.