Advanced Materials

Heterocyclic Microporous Polymers: Hypercrosslinked Aromatic Heterocyclic Microporous Polymers: A New Class of Highly Selective CO2 Capturing Materials (Adv. Mater. 42/2012)

Authors

  • Yali Luo,

    1. Hubei Key Laboratory of Material Chemistry and Service Failure, Key Laboratory for Large-Format Battery, Materials and System, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. China
    Current affiliation:
    1. These authors contributed equally to this work
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  • Buyi Li,

    1. Hubei Key Laboratory of Material Chemistry and Service Failure, Key Laboratory for Large-Format Battery, Materials and System, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. China
    Current affiliation:
    1. These authors contributed equally to this work
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  • Wei Wang,

    1. State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, P.R. China
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  • Kangbing Wu,

    1. Hubei Key Laboratory of Material Chemistry and Service Failure, Key Laboratory for Large-Format Battery, Materials and System, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. China
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  • Bien Tan

    Corresponding author
    1. Hubei Key Laboratory of Material Chemistry and Service Failure, Key Laboratory for Large-Format Battery, Materials and System, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. China
    • Hubei Key Laboratory of Material Chemistry and Service Failure, Key Laboratory for Large-Format Battery, Materials and System, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. China.
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Abstract

On page 5703, Bien Tan and co-workers demonstrate an easy and straightforward route for the preparation of aromatic heterocycle-based microporous organic polymers. Owing to the narrow pore system and the heteroatom-rich pore surface, these networks exhibit large CO2 adsorption capacity and high selectivity toward CO2/N2. The frontispiece shows the density map of the adsorbed CO2 molecules in the simulated microporous structure.

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