Advanced Materials

Atomic Carbide Bonding Leading to Superior Graphene Networks



A versatile method for achieving atomic carbide-bonded graphene networks on both metallic and non-metallic substrates is described. This consists of vacuum-assisted thermal exfoliation and floatation of functional graphenes at elevated temperatures, followed by deposition on substrates and in situ formation of carbide bonds. The cross-linked graphene networks with an interlayer distance of angstroms exhibits a unique combination of unprecedented properties.

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