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Advanced Materials

Phase Separation in Garnet Solid Solutions and its Effect on Optical Properties



Phase behavior is studied in erbium-doped Y3Al5O12 (YAG) garnets synthesized by solid-state reactions. High resolution synchrotron XRD and SEM-EDX studies reveal phase separation at an erbium content between 8 and 50 at%, depending upon the processing conditions. Similar results are found in closely-related garnet systems. The phase separation has a striking effect on the optical properties of YAG:Er3+.

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