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This special issue, guest-edited by Profs. Huisheng Peng and Dongyuan Zhao, celebrates the 20th Anniversary of the Department of Macromolecular Science at Fudan University. The issue presents an overview of the best research in advanced materials at Fudan University. Particular emphasis is paid to functional inorganic and organic materials for the application in energy, catalysis, and biomedical fields, and four typical directions are covered. The front cover shows a landmark building at Fudan University, which is used for teaching and offices. An entrance to the main university campus is shown on the back cover.