Molecules on Si: Electronics with Chemistry (pages 140–159)
Ayelet Vilan, Omer Yaffe, Ariel Biller, Adi Salomon, Antoine Kahn and David Cahen
Version of Record online: 23 OCT 2009 | DOI: 10.1002/adma.200901834
Molecular effects on ransport across metal/organic molecule/semiconductor junctions, in contrast to metal/molecule/metal ones, can be solely electrostatic rather han be the result of the transmittance of molecules. In extremis, this yields metal/insulator/semiconductor (MIS) behavior in structures, apparently without insulator. This Progress Report also considers transport mechanisms, effects of new energy levels from molecule-electrode interactions, and temperature effects on ransport.